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құрылым

A detailed description of the pathway leading from the reactants to the products of a reaction, including as complete a characterization as possible of the composition, structure, and other properties of reaction intermediates and transition states. An acceptable mechanism of a specified reaction (and there may be a number of such alternative mechanisms not excluded by the evidence) trust be consistent with the reaction stoichiometry, the rate law, and with all other available experimental data, such as the stereochemical course of the reaction. Inferences concerning the electronic and nuclear motions which dynamically interconvert successive species along the reaction path (as represented by curved arrows, for example) are often included in the description of a mechanism.

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  • 类别 有机化学
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